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potassium bicarbonate is actually a recommended way for buffering pH.
No problems brewing, most people get it from a brewing supply place actually.
I've never used it personally. I've got plenty of shells and lime available to buffer my system easily so I generally need to add the seaweed extract to get my trace elements plus potassium.
I've got some on order. I thought I'd try it, but I do use a lot of KOH when l want to ease off the hydrated lime or get more results than dolomitic lime. Thanks for the tip on where to get it TC. I'll send my brewer buddy to pick some up next time he goes on a supply run.
It also makes a pretty good foliar spray for powdery mildew...
I use it to not only buffer, but to provide a potassium boost when plants are at the flowering/fruiting/seeding stage...
Otherwise, if I need to pull the pH back I use Calcium Hydroxide... mainly because it's so readily, and cheaply, available compared to Potassium Hydroxide...
Calcium Hydroxide is often known as "slaked",, or "hydrated" lime.... commonly used by brickies...
It's actually marketed here in Australia as an approved "organic" fungacide... EcoRose...
https://www.ecoorganicgarden.com.au/upload/EcoRose%20label-BFA.pdf
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